In the Magento administrator area go to
System -> Import/Export -> Dataflow - Profiles -> Export All Products.
Under Profile Information -> Store choose the desired store where you will be importing the products.
This should also match the store where you have previously created a sample product. Under Data Transfer drop down menu choose Local/Remote Server.
Under Data Format make sure CSV / Tab Separated is selected for type and click Save Profile. Then click export all products again and click Run Profile in Popup.
This will save a file named “exportallproducts.csv” under the var/export/ directory for your Magento installation. The export success screen will look like this and will specify the file name where the products were exported.
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